| • मैडेलुंग स्थिरांक • मैडैलुंग नियतांक | |
| constant: अचलराशि नियत | |
madelung constant मीनिंग इन हिंदी
madelung constant उदाहरण वाक्य
उदाहरण वाक्य
अधिक: आगे- For instance, the Madelung constant then reads
- There occur as many Madelung constants M _ i in a crystal structure as ions occupy different lattice sites.
- These second order Madelung constants turned out to have significant effects on the lattice energy and other physical properties of heteropolar crystals.
- For example, for the ionic crystal NaCl, there arise two Madelung constants & ndash; one for Na and another for Cl.
- The nearest neighbour distance amounts to half the lattice parameter of the cubic unit cell r _ 0 = a / 2 and the Madelung constants become
- This graph demonstrates the non-convergence of the expanding spheres method for calculating the Madelung constant for NaCl as compared to the expanding cubes method, which is convergent.
- The polarisation can be calculated on the basis of higher-order Madelung constants and has to be included in the calculation of the lattice energy by using a generalised Born Haber cycle.
- The Ewald summation was developed by Paul Peter Ewald in 1921 ( see References below ) to determine the electrostatic energy ( and, hence, the Madelung constant ) of ionic crystals.
- The electrostatic interaction model of ions in solids has thus been extended to a point multipole concept that also includes higher multipole moments like dipoles, quadrupoles etc . These concepts require the determination of higher order Madelung constants or so-called electrostatic lattice constants.
